as others have said, you wont get anything out of putting it in the gas. Other than slightly cleaner injectors (maybe), and some fuel stabilization.
If your car is turbo (noticed its an audi a6). You may get some benefit of adding to the oil or through the manifold to burn off any sludging that could possibly have happened in that 25k miles, which i doubt is very much.
For the bottom end, you'd probably reap similar benefits from using a motor oil with a lot of cleaners (pennzoil platinum or ultimate) for a few oil changes, its been pretty well documented on bobistheoilguy.com forums that it cleans up internals pretty nice.
I'd wait till about 50 or 60k to do it on the top end, then change your plugs etc as a 60k service.
I thought i had the lowes mileage 04 around with 31,000... looks like you win.