If you were very careful not to overwork, the only other possibility is that the clear coat was thinned some much by someone else, then you going over it took it over the edge and burned through.
Its really not the end of the world tbh, many paint systems before did not have clear coats.
If it really bugs you (it would sicken me tbh), I would take it straight to a good body shop or painter with a proper booth (id go to a painter, they are better with stuff like this) and get them to fix it. Depending on the conditions, they respray the entire panel or re-clear it.
Remember that DA buffers are safer, but not fool proof. The Griots (particularly powerful), can generate quite a bit of heat. Heat burns paint and if held on a body line or edge for even a few seconds due to the high concentration of power on one point.
Also remember (nerd time), Corvettes are all fibreglass and plastic. Compared to aluminum or ferrous metal panels, composite materials do not dissipate heat very well, in fact they act like an insulator. So on any composite body parts, you have to be even more conscious about heat because it builds faster.
Larry at AMMONYC demonstrates this best [ame=http://www.youtube.com/watch?v=htsl7ICY8Nw]$1,000,000 Ferrari Restoration Detail - YouTube[/video]
Hope this works out for you!!