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Eh, I've had PDR done with no additional heat added before. Completely depends on the type of dent, it's location, and/or skill set of the PDR technician.
Wet the panel. If the water behavior in that area appears different, polish and re-coat.
I can't imagine the coating being less flexible than the paint itself, but you could always recoat it to give you peace of mind.
Should be fine as long as it's not a glue pull and there is no additional tapping required on the paint side.
My only concern would be marring from the process, not the coating failing.