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Andy I have used a waterless in temps down to about 20 but the product itself was stored indoors prior to use and was about 70 degrees itself. Any colder and I use a rinse less with warm water in it.
It`s important to remember the wind chill factor as well. Even though it may be 30 degrees, it can be a bit cooler under a car port and factor in even cooler with the wind. I usually error on the side of caution. If its so cold where you are struggling to wash your car, just wait for it to warm up a bit. Yes, I know it sucks, but I`ve been there. I spent 7 years in Syracuse and I didnt have a garage for a few. Luckily, I found a pay & spray where the doors closed and I would go late at night there and wash using their water but my buckets pre filled with warm water.
Wind does not change the ambient air temperature.
Wind does not change the ambient
air temperature.
Aren't both of these casesTry rolling all your windows down while
driving in freezing cold temperatures.
Maybe ride a motorcycle in the same
freezing cold temperatures.
Then come back and report.
lol.
Windchill cannot cause something to freeze... for instance, if ambient temps are 40 degrees, but with windchill it "feels like" 30 degrees, a bucket of water will not freeze if left outside.
However, to the OP's question, if a vehicle is outdoors in 20 degree weather, rinseless or waterless wash solution can certainly freeze on the surface even if you are using warm water as the thin layer of water that is on the car will cool rapidly when the surface temp of the vehicle is 20F. You may be able to work quickly and avoid freezing, however I'd simply wait for temps to be above or very near freezing... or find a sheltered area to wash in.
Three days ago, I did a Dodge Ram 2500 with Optimum No Rinse Wash and Wax with temperatures around 29 degrees F. I used warm water, did one panel at a time, and worked quickly.
My process: spray panel with ONR solution. Keep bucket of warm solution with 15 clean towels in the solution. Wipe panel with towel using clean surface for each wipe. Dry with waffle weave. Move to next panel.
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What about when it says it's 20 degrees out and wind chill is -10? It sure as hell feels colder than 20 degrees.