First I would recommend getting yourself a practice hood so you don't destroy your paint job while you tame the rotary beast. Secondly, don't try and force the machine to go in a certain direction, instead gently guide it. Using a polishing pad, and a polish with a long working time (try OPT Polish.) Try out the machine a 1100rpm (slowest) and without putting any pressure on the pad, set it on the panel you are working on and get a feel for where the machine wants to go. Try moving it side to side, and canting it slightly in different directions to get an understanding of its natural movements. Every panel is different, sometimes you have no choice but to tilt the buffer slightly to follow the curvature of certain panels, however you must remember to keep the pad as flat as possible at all times. Buffer hop is a pain, but it can be overcome with practice, and varying the buffers position.
The biggest mistake you can make is to use the pad at such an angle where you're almost grinding away with the edge of a pad. Big mistake, this could cause some serious damage since great amounts of heat will be generated.
While you are polishing, touch the panel section you are polishing frequently to make sure the paint doesn't get too hot. If you touch it and it makes you want to recoil your palm back to safety, then the panel is too hot (stop.) I've seen too many people buff at really high speeds with their polishers which really doesn't do all that much good.
Instead, slow the RPM speed as well as your arm speed. This practice will allow the polish adequate time to properly polish the area you are working, and is less likely to cause other problems down the road (like holograms*.)
In short, the best thing you can do is practice. Don't get too frustrated, go in there with an open mind, mistakes will be made, but learn from them. I suggest you go out every other day to the garage and practice for an hour or so. Sooner or later you'll start to get the hang of it. It takes time, practice and patience.
* Most pad/ polish choices will induce some holograms (that's why you'll have a DA with you at all times.) The key is to induce the faintest ones possible. Practice enough and sooner or later you'll be able to finish down hologram free with you rotary on certain paint types (not possible on all paint, it all depends.):xyxthumbs: