My theory on the order to apply... I'm just guessing the 845 has a higher load of distillates in it in order to make it liquid (it will haze/evaporate off). I'd apply 845 first, out of concern that the distillates in the 845 would essentially liquefy (dissolve) a portion of the 476 if it were previously applied. The same thing will happen if you reversed the order, but to a lesser degree. Make sense?
Per product weight, the 476 probably has a higher "wax" load and wouldn't be as hard on whatever was underneath it.
I don't think this is a question of the most durable product being laid down first, as with topping a sealant with a wax. I've heard that the 476/845 are similar in composition. 476 is more durable in that it has a higher percentage of wax remaining on the surface after buffing (i.e. More wax laid down per area upon application). But in this case, I'd put the one with the least capacity to dissolve on first (the 476).
Again, just a theory. But to be honest, If I was doing two coats regardless, I'd do two coats of 476. Why not use the most durable product twice?